[μ-1,2-Bis(salicyloyl)hydrazine(4−)]bis[(ethylenediamine)zinc(II)] dimethylformamide disolvate dihydrate

Autor:	Shi-Xiong Liu, Zeng-You Wang
Rok vydání:	2007
Předmět:	Diazine Hydrogen bond Stereochemistry Ligand Hydrazine chemistry.chemical_element Ethylenediamine General Chemistry Zinc Condensed Matter Physics chemistry.chemical_compound Crystallography chemistry Dimethylformamide General Materials Science Coordination geometry
Zdroj:	Acta Crystallographica Section E Structure Reports Online. 63:m3105-m3106
ISSN:	1600-5368
DOI:	10.1107/s1600536807057212
Popis:	In the title compound, [Zn2(C14H8N2O4)(C2H8N2)2]·2C3H7NO·2H2O, the Zn2 complex mol­ecule lies on a crystallographic inversion centre. The two Zn atoms are bridged by two diazine N atoms of a 1,2-bis­(salicylo­yl)hydrazine(4−) ligand (bsh4−); the inversion centre is located at the mid-point of the N—N bond. The coordination geometry of the Zn atom is distorted square-pyramidal. Each water mol­ecule is linked with three surrounding binuclear complexes through four hydrogen bonds, resulting in a two-dimensional network.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3b5dd9d35bf4190a9aaf203723c59c0a https://doi.org/10.1107/s1600536807057212 Zobrazit plný text záznamu Plný text ve formátu PDF