A convenient one-pot synthesis of 1,2-azaphospholanium salts

Autor:	Tatyana A. Mastryukova, Konstantin A. Lyssenko, D. I. Lobanov, Olga V. Bykhovskaya, Pavel V. Petrovskii, I. M. Aladzheva
Rok vydání:	2003
Předmět:	Hydrolysis Chemistry Intramolecular force Phosphorus One-pot synthesis Heteroatom Organic chemistry chemistry.chemical_element General Chemistry Alkylation Probable mechanism
Zdroj:	Heteroatom Chemistry. 14:596-602
ISSN:	1098-1071 1042-7163
DOI:	10.1002/hc.10209
Popis:	A novel facile one-pot synthesis of the 1,2-azaphospholanes by intramolecular alkylation of 3-halopropyl amides of tricoordinate phosphorus has been suggested. Using this method, a series of the differently N-substituted 1,2-azaphospholanium salts were synthesized. 3-Aminopropylphosphine oxides were obtained by hydrolysis of the salts. A probable mechanism of the 1,2-azaphospholanium salts formation is discussed. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:596–602, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10209
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3b5a9241158c68b7c20a2132e920a04b https://doi.org/10.1002/hc.10209 Zobrazit plný text záznamu