Radiation-induced binding of 2,2,6,6-tetramethyl-1,4-piperidone-N-oxyl to thymidine in oxygen-free aqueous solutions. Isolation and characterization of the adducts

Autor:	Jacques Ulrich, Jean Cadet, M. Berger
Rok vydání:	1985
Předmět:	Aqueous solution Organic Chemistry Nitroxyl General Chemistry Nuclear magnetic resonance spectroscopy Carbon-13 NMR Mass spectrometry Catalysis Adduct chemistry.chemical_compound chemistry Organic chemistry Thymidine Nucleoside Nuclear chemistry
Zdroj:	Canadian Journal of Chemistry. 63:6-14
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v85-002
Popis:	Steady-state γ-radiolysis of deaerated aqueous solutions of thymidine has been carried out in the presence of 2,2,6,6-tetramethyl-1,4-piperidone-N-oxyl (TAN), a well-known radiosensitizing agent. The eight main radiation-induced TAN addition products to thymidine have been isolated and characterized by 1H and 13C nmr, cd, and fast-atom bombardment mass spectrometry measurements.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3b45c6675b9bb69f48e28811e99ab591 https://doi.org/10.1139/v85-002 Zobrazit plný text záznamu