Novel Dimeric Organotin Cations: Highly Effective Alcohol Acetylation Catalysts

Autor:	and Akihiro Orita, Haruo Akashi, Yuuki Hamada, Junzo Otera, Katsumasa Sakamoto
Rok vydání:	1999
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Acetylation Organic Chemistry Organic chemistry Alcohol Physical and Theoretical Chemistry Catalysis
Zdroj:	Organometallics. 18:3555-3557
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om990412k
Popis:	Novel organotin cations, [R2SnOH(H2O)]22+(OTf)-2 (R = n-Bu and t-Bu), were prepared from R2SnO and CF3SO3H (TfOH). The synthetic utility of these compounds due to the increased Lewis acidity was exemplified by their high catalytic activity in the acetylation of alcohols.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3b3982967672201ec20f5b195bb890a7 https://doi.org/10.1021/om990412k Zobrazit plný text záznamu