OXIDATION OF SULFIDES BY IODYLARENES IN THE PRESENCE OF VANADYL ACETYLACETONATE AS A CATALYST

Autor:	P. Bordat, B. Tinland, F. Pautet, M. Daudon, R. Barret
Rok vydání:	1989
Předmět:	Organic Chemistry Inorganic chemistry chemistry.chemical_element Sulfoxide Biochemistry Sulfur Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Yield (chemistry) Organic chemistry Vanadyl acetylacetonate Selectivity
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 45:31-33
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426508908046073
Popis:	Iodylbenzene is a poor oxidant of sulfur, but in the presence of vanadyl acetylacetonate, sulfides are converted into sulfoxides, sulfones and S-dealkylated products. To improve the selectivity and the yield of this reaction, different substituted iodylarenes are used. The N-(paraiodylphenyl) palmitoyl-amid is a promising oxidant for synthetic purposes.
Databáze:	OpenAIRE
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