Conducting radical salts of the new electron donor bis(1.3-cyclobutylenedithio)tetrathiafulvalene
| Autor: | M. Schiller, I Löb, T. Klausa, W. Strunz, I. Heinen, Hans Pritzkow, Dieter Schweitzer, M Hübler, W. Schmidt, Heimo J. Keller, C Milbredt, P. Kircher |
|---|---|
| Rok vydání: | 2001 |
| Předmět: |
chemistry.chemical_classification
Mechanical Engineering Inorganic chemistry Metals and Alloys Electron donor Crystal structure Condensed Matter Physics Electrochemistry Electronic Optical and Magnetic Materials chemistry.chemical_compound Polycyclic compound chemistry Mechanics of Materials Electrical resistivity and conductivity Hexafluorophosphate Polymer chemistry Materials Chemistry Molecule Tetrathiafulvalene |
| Zdroj: | Synthetic Metals. 122:279-286 |
| ISSN: | 0379-6779 |
| DOI: | 10.1016/s0379-6779(00)00303-9 |
| Popis: | The new π -electron donor bis(1.3-cylobutylenedithio)tetrathiafulvalene (1.3-CBDT-TTF), which is only slightly different in the periphery of the molecule with respect to the well-known donor BEDT-TTF, was synthesized. The molecular structure has been characterized and the electrochemical behavior of this new donor was investigated. New cation radical salts were prepared by electrocrystallization methods. The structures of (1.3-CBDT-TTF)I 2 , (1.3-CBDT-TTF) 2 [AuI 2 ], (1.3-CBDT-TTF) x (ReO 4 ) y and (1.3-CBDT-TTF) 2 PF 6 ·THF were characterized by X-ray analyses. The room temperature electrical resistivities of the radical salts are low and range between 0.5 and 5 Ω cm. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect