Interaction of cumylperoxy radicals with aliphatic monocarboxylic acid esters

Autor:	N. I. Mitskevich, V. E. Agabekov, G. V. Butovskaya, T. G. Kosmacheva
Rok vydání:	1975
Předmět:	chemistry.chemical_classification Bond strength Radical Hydrogen atom abstraction Catalysis chemistry.chemical_compound Reaction rate constant chemistry Chlorobenzene Propionate Organic chemistry Physical and Theoretical Chemistry Isopropyl
Zdroj:	Reaction Kinetics and Catalysis Letters. 2:123-128
ISSN:	1588-2837 0133-1736
DOI:	10.1007/bf02060962
Popis:	The oxidation rates of different monocarboxylic acid esters have been determined in the presence of cumyl hydroperoxide at 50–115°C, in chlorobenzene solution. The rate constants of hydrogen atom abstraction by cumylperoxy radicals have been calculated for methyl, ethyl, isopropyl and t-butyl propionate and t-butyl isobutyrate. The C-H bond strengths in the esters studied have been estimated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3af2bce7d3437e759265963e36193f9d https://doi.org/10.1007/bf02060962 Zobrazit plný text záznamu Full text from SpringerLink