Hydrolysis of Diribonucleoside Monophosphate Diesters Assisted by a Manganese(II) Complex

Autor:	Youichi Ishii, Morio Yashiro, Maiko Higuchi, Makoto Komiyama
Rok vydání:	2003
Předmět:	Hydrolysis Chemistry Stereochemistry Diphenyl phosphate Phosphodiester bond chemistry.chemical_element Molecule General Chemistry Manganese Medicinal chemistry
Zdroj:	Bulletin of the Chemical Society of Japan. 76:1813-1817
ISSN:	1348-0634 0009-2673
DOI:	10.1246/bcsj.76.1813
Popis:	An Mn2+ complex with 2,2′:6′,2″-terpyridine (terpy) was found to promote the hydrolysis of NpN (NpN = diribonucleoside monophosphate diester) efficiently at pH 7.0 and 50 °C under ambient conditions. The structure of the Mn2+ complex involving a phosphodiester molecule, [(terpy)(dpp)MnII(μ-dpp)2MnII(dpp)(terpy)], dpp = diphenyl phosphate anion, was established by X-ray crystallography, and the coordination mode of Mn2+ to a phosphodiester molecule was considered.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3aeed2731ef560fdb5af224bde4db436 https://doi.org/10.1246/bcsj.76.1813 Zobrazit plný text záznamu