Approximate energy spectra and statistical mechanical functions of some diatomic molecular hydrides
| Autor: | Hewa Y. Abdullah, Gaotsiwe Joel Rampho, Uduakobong S. Okorie, Akpan N. Ikot |
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| Rok vydání: | 2021 |
| Předmět: |
Physics
General Physics and Astronomy Euler–Maclaurin formula 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Diatomic molecule Spectral line 0104 chemical sciences Schrödinger equation symbols.namesake Vibrational partition function Quantum mechanics Physics::Atomic and Molecular Clusters symbols Physics::Chemical Physics 0210 nano-technology Energy (signal processing) |
| Zdroj: | Canadian Journal of Physics. 99:253-258 |
| ISSN: | 1208-6045 0008-4204 |
| Popis: | In this study, we have investigated the statistical mechanical properties of the Varshni potential model for some diatomic molecular hydrides via the Euler–Maclaurin formula. This was done using the approximate analytical energy eigenvalues, which were obtained by solving the radial Schrödinger equation with the Greene–Aldrich approximation and suitable coordinate transformation schemes. The effect of high temperatures and upper bound vibration quantum number on the vibrational partition function and other thermodynamic functions of the selected diatomic molecular hydrides were studied. We also show that these effects on the thermodynamic functions considered were similar for all the diatomic molecular hydrides selected. |
| Databáze: | OpenAIRE |
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