A Case for Mechanisms
| Autor: | Tim den Hartog, Peter Chen, Stefan A. Künzi, Juan Manuel Sarria Toro |
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| Rok vydání: | 2015 |
| Předmět: | |
| Zdroj: | Israel Journal of Chemistry. 56:53-61 |
| ISSN: | 0021-2148 |
| Popis: | A case study in the (re)discovery of a non-diazo, catalytic, electrophilic cyclopropanation reaction is presented to illustrate the role of mechanistic concepts in chemical innovation. The specific instance also highlights how specific personalities interacted in the report, retraction, and reconsideration of a novel methylene transfer reaction. The case study ends with a series of lessons learned, which generalize the findings from the specific case. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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