Oxazoline-functionalized hydrogenated nitrile rubber as impact modifier for polyamide-6

Autor:	M. Wlaźlak, J. Pigłowski, I. Gancarz
Rok vydání:	2000
Předmět:	Materials science Polymers and Plastics Nitrile Organic Chemistry Chemical modification Oxazoline Miscibility chemistry.chemical_compound chemistry Natural rubber visual_art Polyamide Polymer chemistry Materials Chemistry visual_art.visual_art_medium Organic chemistry Polymer blend Nitrile rubber
Zdroj:	Polymer. 41:3671-3681
ISSN:	0032-3861
DOI:	10.1016/s0032-3861(99)00596-0
Popis:	Hydrogenated nitrile rubber (Therban) was modified in the solution and in the melt to introduce oxazoline units into the chain. Conversion of nitrile groups reached about 40% what corresponds 13.6 mol% of oxazoline units in the modified sample. The chemical structure of product was confirmed by FTIR and 2D NMR spectra. To calculate the degree of conversion from IR spectra, correlation between 1 H NMR and IR data was found. Blends of modified samples with polyamide-6 were prepared. DSC data seem to indicate the partial miscibility of blend components as a result of the creation of covalent bonds between them. By addition of modified rubber, impact strength of the polyamide was highly improved.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3ad514c056de468a6cba5c41eaa6cc9e https://doi.org/10.1016/s0032-3861(99)00596-0 Zobrazit plný text záznamu Full Text from ScienceDirect