Crystal Structure, Luminescence and Triboluminescence of the Complex [Eu(NO3)23hmpa] NO3·HQuin
| Autor: | I V Kalinovskaya, B. V. Bukvetskii |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Sociology and Political Science
Chemistry Quinaldic acid Clinical Biochemistry 02 engineering and technology Crystal structure 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Biochemistry Triboluminescence 0104 chemical sciences Crystal Clinical Psychology Crystallography Molecule 0210 nano-technology Luminescence Law Spectroscopy Social Sciences (miscellaneous) |
| Zdroj: | Journal of Fluorescence. 27:773-779 |
| ISSN: | 1573-4994 1053-0509 |
| DOI: | 10.1007/s10895-016-2009-7 |
| Popis: | The atomic structure of crystals of the complex [Eu(NO3)23hmpa] NO3·HQuin , (hmpa – hexamethylphosphortriamide, HQuin – quinaldic acid) characterized by intensive luminescence and triboluminescence has been determined by the X-ray method. The noncentro-symmetric crystals of the compound are rhombic : a = 16.8193(3), b = 12.2877(2), c = 27.6516(5) A, пр. гр. Pca2(1), Z = 4, ρ calc. . = 1.427 g/сm3. The crystals have a structure of the insular type which is presented by the isolated complex molecules, outer-sphere NO3 − – groups, and neutral molecules of quinaldic acid. Some structural aspects of formation of the luminescent and triboluminescent properties of the compound were discussed: the role of break planes in the crystal destruction was revealed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink