Determination of the solubility behavior of some polycyclic aromatic hydrocarbons in water

Autor:	Willie E. May, Stanley P. Wasik, David H. Freeman
Rok vydání:	1978
Předmět:	chemistry.chemical_compound Hildebrand solubility parameter Aqueous solution Chromatography Hydrogen compounds chemistry Aqueous solubility Inorganic chemistry Enthalpy Solubility Benzene Analytical Chemistry Naphthalene
Zdroj:	Analytical Chemistry. 50:997-1000
ISSN:	1520-6882 0003-2700
DOI:	10.1021/ac50029a042
Popis:	The dynamic coupled column liquid chromatographic (DCCLC) method for determining the solubility of polycyclic aromatic hydrocarbons (PAH) in water is described. The DCCLC technique is a very rapid, precise, and accurate method for determining the aqueous solubility behavior of sparingly soluble organic compounds. The agreement of PAH aqueous solubilities and calculated solubility parameters, such as ..delta..Hs, with values that have been previously reported in the literature helps to confirm the validity of this approach. In all cases replicate solubility measurements of the generated PAH solutions at constant temperature were better than +- 3 percent and in most cases better than +- 1%. The lack of an appropriate physical parameter for accurately extrapolating PAH solubilities further enhances the utility of DCCLC method.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3aa0390f4c4e594ca85f7bf3122e1b5e https://doi.org/10.1021/ac50029a042 Zobrazit plný text záznamu