Co-ordination complexes containing multidentate ligands. Part III. The visible spectra of some five-co-ordinate nickel(II) complexes containing tris(o-dimethylarsinophenyl)stibine. Trigonal bipyramidal and square pyramidal complexes

Autor:	Charles A. McAuliffe, Michael T. Halfpenny, Livio Baracco
Rok vydání:	1973
Předmět:	Tris Denticity Stibine Stereochemistry Co ordinate chemistry.chemical_element General Chemistry Spectral line Square pyramidal molecular geometry Trigonal bipyramidal molecular geometry chemistry.chemical_compound Nickel Crystallography chemistry
Zdroj:	Journal of the Chemical Society, Dalton Transactions. :1945
ISSN:	1364-5447 0300-9246
DOI:	10.1039/dt9730001945
Popis:	The trisubstituted stibine, tris(o-dimethylarsinophenyl)stibine (sbta) reacts with nickel(II) salts to form complexes of type [Ni(sbta)X]Y (X = Cl, Br, I, NCS, and NO3; Y = Cl, Br, I, CNS, NO3, and BPh4) and [Ni(sbta)2]Z2(Z = ClO4 and BPh4). These diamagnetic complexes are five-co-ordinate, the [Ni(sbta)X]+ species being trigonal bipyramidal while the [Ni(sbta)2]2+ species are square pyramidal. The visible spectra of these complexes are discussed and compared with those of other complexes containing ligands with the SbAS3 and As4 donor sets.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3a9a90a3873ef740781d545c7b8f09ad https://doi.org/10.1039/dt9730001945 Zobrazit plný text záznamu