Nature of active sites in the oxidative coupling of methane to ethane over Li/MgO catalysts
| Autor: | Kent E. Coulter, Charles M. Truong, Ming-Cheng Wu, D. Wayne Goodman |
|---|---|
| Rok vydání: | 1993 |
| Předmět: |
chemistry.chemical_classification
Chemistry Inorganic chemistry chemistry.chemical_element Surfaces and Interfaces Condensed Matter Physics Heterogeneous catalysis Chemical reaction Methane Surfaces Coatings and Films Catalysis chemistry.chemical_compound Hydrocarbon Lithium Oxidative coupling of methane Partial oxidation |
| Zdroj: | Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. 11:2174-2178 |
| ISSN: | 1520-8559 0734-2101 |
| DOI: | 10.1116/1.578388 |
| Popis: | The partial oxidation of methane to ethane over a model Li/MgO catalyst has been studied using combined surface science techniques/elevated pressure kinetic measurements. The results indicate that [Li+O−] centers are not likely directly involved in the methane activation step. Rather, addition of lithium promotes the production of F centers which are considered to be responsible for this key step in the methane coupling reaction. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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