Intramolecular cyclization of ortho-alkynylanilines by Rh(I)-catalyzed hydroamination to yield benzo(dipyrroles)

Autor:	Leslie D. Field, Peter Turner, Adelle Shasha, Guy K. B. Clentsmith, Barbara A. Messerle
Rok vydání:	2009
Předmět:	Chemistry Yield (chemistry) Intramolecular force Organic Chemistry Drug Discovery Intramolecular cyclization Organic chemistry Hydroamination Biochemistry Medicinal chemistry Catalysis
Zdroj:	Tetrahedron Letters. 50:1469-1471
ISSN:	0040-4039
Popis:	The methylene-bridged Rh(I) dicarbonyl complex, [ Rh(bim) (CO) 2 + BPh 4 - ] (1) (bim = bis(N-methylimidazol-2-yl)methane), is an effective catalyst for the intramolecular hydroamination of selected ortho-alkynylanilines to give a range of benzo(dipyrroles).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3a8af8d5da9b0f9cbc33562c3de444a5 https://doi.org/10.1016/j.tetlet.2009.01.060 Zobrazit plný text záznamu Full Text from ScienceDirect