Steric strain in syn[2.2]Metacylophane
| Autor: | Yoshisuke Nakasato, Hideaki Hioki, Yoshimasa Fukazawa, Miwa Nagaku, Shô Itô, Yutaka Fujise |
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| Rok vydání: | 1993 |
| Předmět: | |
| Zdroj: | Tetrahedron Letters. 34:3787-3788 |
| ISSN: | 0040-4039 |
| Popis: | conformation of syn-5,13-dimethyl[2.2]metacyclophane was established by X-ray crystallographic analysis, and its steric energy evaluated by MM2 calculations. Based on these data the steric strain inherited in the compound was concluded to originate mainly from the nearly eclipsed conformation of two ethano bridges. |
| Databáze: | OpenAIRE |
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