Synthesis and electrochemical properties of tetrathienyl-linked branched polymers with various aromatic cores
| Autor: | Carlo Fasting, Krzysztof R. Idzik, Przemyslaw Ledwon, Tobias Licha, Mieczyslaw Lapkowski, Carsten Müller, Rainer Beckert, Jaroslaw Frydel |
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| Rok vydání: | 2012 |
| Předmět: |
Materials science
Organic solar cell General Chemical Engineering 02 engineering and technology Carbon-13 NMR 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences Fluorescence spectroscopy 0104 chemical sciences chemistry.chemical_compound Monomer chemistry Elemental analysis Electrochemistry Proton NMR OLED Physical chemistry Cyclic voltammetry 0210 nano-technology |
| Zdroj: | Electrochimica Acta. 79:154-161 |
| ISSN: | 0013-4686 |
| Popis: | A series of various tris(2,2′-bithiophen-5-yl)-aromatic derivatives were synthesized by Stille cross-coupling procedure. Their structures were characterized by 1H NMR, 13C NMR, and elemental analysis. DFT calculations for monomers were also performed. The optical properties of the synthesized materials as well as their energy levels were investigated by UV–vis absorption supported by fluorescence spectra and CV analysis. Oligomers obtained in the process of electropolymerization, possess a tetrathienyl bond with various aromatic and heteroaromatic cores. Electrochemical results confirm that the gained materials can apply successfully for a diversity of organic–electronic devices like organic light-emitting diodes (OLEDs), organic field-effect transistors (OFETs), and organic solar cells. |
| Databáze: | OpenAIRE |
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