Miscibility, mechanical, and thermal properties of polylactic acid/polypropylene carbonate (PLA/PPC) blends prepared by melt-mixing method
Autor: | Sharifah Imihezri Syed Shaharuddin, Norhashimah Shaffiar, Yose Fachmi Buys, Intan Najwa Humaira Mohamed Haneef, M.K. Nor Khairusshima |
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Rok vydání: | 2019 |
Předmět: |
010302 applied physics
Materials science Scanning electron microscope 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences Miscibility chemistry.chemical_compound Differential scanning calorimetry Polylactic acid chemistry Chemical engineering 0103 physical sciences Polypropylene carbonate Elongation Fourier transform infrared spectroscopy 0210 nano-technology Glass transition |
Zdroj: | Materials Today: Proceedings. 17:534-542 |
ISSN: | 2214-7853 |
DOI: | 10.1016/j.matpr.2019.06.332 |
Popis: | In this project, Polylactic acid (PLA) and Polypropylene carbonate (PPC) blends were prepared using melt-mixing method to overcome its brittleness. The tensile test results showed that the elongation at break increased from 6% of the neat PLA to 13% as 7.5% of PPC was added. A more significant increase of elongation at break of the blends from 13% to 68% was observed as the amount of PPC was increased to 15%. The highest elongation at break achieved up to 173% when 30% of PPC was added. From differential scanning calorimetry (DSC) analysis, two glass transition temperatures ( T g ) were observed. As the amount of PPC increased, T g of PLA was shifted to a lower temperature and vice versa, indicating PLA and PPC were partially miscible. Scanning Electron Microscopy (SEM) verified PPC, with a uniform size, were homogeneously distributed in PLA matrix. Finally, Fourier Transform Infrared (FTIR) measurement revealed that there was a shift of wavenumber from 2997 cm1 and 2949 cm-1 to 2990 cm-1 and 2960 cm-1 which explained that there was a possible intermolecular interaction between –CH of PLA and –O-C or –O=C of PPC which influenced the partial miscible of the blends. |
Databáze: | OpenAIRE |
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