Temperature-programmed surface reactions of methanol on commercial Cu-containing catalysts

Autor:	A. Y. Rozovskii, G. I. Lin, Kh. M. Minachev, K. P. Kotyaev
Rok vydání:	1989
Předmět:	Methyl formate Inorganic chemistry General Chemistry Chemical synthesis Catalysis chemistry.chemical_compound Hydrolysis Adsorption chemistry Transition metal Polymer chemistry Methanol Organometallic chemistry
Zdroj:	Catalysis Letters. 3:299-307
ISSN:	1572-879X 1011-372X
DOI:	10.1007/bf00766067
Popis:	Temperature-programmed reaction spectroscopic studies reveal two main transformation routes of methanol adsorbed on commercial Cu-containing catalysts. First the reverse methanol synthesis reaction (hydrolysis) CH3OH+H2O=CO3+3H2; a second route is not connected with CH3OH synthesis and it includes bimolecular interaction of methanol giving methyl formate. The conversion of the latter compound results in the formation of CO, and other intermediates often postulated in methanol synthesis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3a54c8ccc5399558be418b37f2ea89ba https://doi.org/10.1007/bf00766067 Zobrazit plný text záznamu Full text from SpringerLink