Two interpenetrating CuII/NiII-coordinated polymers based on an unsymmetrical bifunctional N/O-tectonic: Syntheses, structures and magnetic properties
| Autor: | Ya-Pan Wu, Yong-Liang Liu, Wen-Wen Dong, Chun-Sheng Zhou, Dongsheng Li |
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| Rok vydání: | 2015 |
| Předmět: |
chemistry.chemical_classification
Materials science Stereochemistry Polymer Crystal structure Condensed Matter Physics Magnetic susceptibility Electronic Optical and Magnetic Materials Inorganic Chemistry Paramagnetism Crystallography chemistry.chemical_compound chemistry Nickel compounds Materials Chemistry Ceramics and Composites Physical and Theoretical Chemistry Bifunctional Single crystal |
| Zdroj: | Journal of Solid State Chemistry. 223:38-43 |
| ISSN: | 0022-4596 |
| Popis: | Two new interpenetrating Cu{sup II}/Ni{sup II} coordination polymers, based on a unsymmetrical bifunctional N/O-tectonic 3-(pyrid-4′-yl)-5-(4″-carbonylphenyl)-1,2,4-triazolyl (H{sub 2}pycz), ([Cu-(Hpycz){sub 2}]·2H{sub 2}O){sub n} (1) and ([Ni(Hpycz){sub 2}]·H{sub 2}O){sub n} (2), have been solvothermally synthesized and structure characterization. Single crystal X-ray analysis indicates that compound 1 shows 2-fold parallel interpenetrated 4{sup 4}-sql layers with the same handedness. The overall structure of 1 is achiral—in each layer of doubly interpenetrating nets, the two individual nets have the opposite handedness to the corresponding nets in the adjoining layers—while 2 features a rare 8-fold interpenetrating 6{sup 6}-dia network that belongs to class IIIa interpenetration. In addition, compounds 1 and 2 both show similar paramagnetic characteristic properties. - Graphical abstract: Two new Cu(II)/Ni(II) coordination polymers present 2D parallel 2-fold interpenetrated 4{sup 4}-sql layers and a rare 3D 8-fold interpenetrating 6{sup 6}-dia network. In addition, magnetic susceptibility measurements show similar paramagnetic characteristic for two complexes. - Highlights: • A new unsymmetrical bifunctional N/O-tectonic as 4-connected spacer. • A 2-fold parallel interpenetrated sql layer with the same handedness. • A rare 8-fold interpenetrating dia network (class IIIa) |
| Databáze: | OpenAIRE |
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