Autor:	G. Ya. Rudinskaya, A. T. Serkov, A. T. Kalashnik, O. N. Panichkina
Rok vydání:	2001
Předmět:	chemistry.chemical_classification Materials science chemistry General Chemical Engineering General Materials Science General Chemistry Polymer Composite material Elasticity (economics) Shrinkage Macromolecule
Zdroj:	Fibre Chemistry. 33:132-139
ISSN:	0015-0541
DOI:	10.1023/a:1019265020422
Popis:	Shrinkage processes in two types of acrylic fibres in heating in air in different regimes in the 50-250°C temperature region were investigated by a thermomechanical method. The mechanisms of the shrinkage were revealed in heating—cooling cycles and its partial reversibility and relation with the cyclization reaction was demonstrated. The irreversible part of shrinkage of the fibers is due to cyclization and relaxation of the macromolecules, while reversible shrinkage is due to the entropic elasticity of the polymer macromolecules.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3a3b910e1733f6aebfb63a3230b11a7a https://doi.org/10.1023/a:1019265020422 Zobrazit plný text záznamu Full text from SpringerLink