35Cl NQR study of 2,6-dichlorotoluene
| Autor: | A.H. Brunetti, J.L. Caccia, D.J. Pusiol |
|---|---|
| Rok vydání: | 1989 |
| Předmět: |
Chemistry
Organic Chemistry Relaxation (NMR) Solid-state Spin–lattice relaxation Atmospheric temperature range Chloride Toluene Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound Nuclear magnetic resonance Intramolecular force medicine Physical chemistry Spectral data Spectroscopy medicine.drug |
| Zdroj: | Journal of Molecular Structure. 195:319-324 |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/0022-2860(89)80178-4 |
| Popis: | The temperature dependence of the NQR frequencies and spin—lattice relaxation time of 2,6-dichlorotoluene are investigated in the temperature range 60–160 K. From the NQR spectral data a possible molecular arrangement is suggested. Besides, the observed T 1 ( T ) behaviour can be explained by using the proposed molecular arrangement, by assuming a relaxation mechanism provided by the intramolecular interaction between the Cl nuclei and the methyl groups. The results are well correlated with those obtained in a previously studied substituted toluene compound, p -toluenesulphonyl chloride. |
| Databáze: | OpenAIRE |
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