Electronically Weak Coupled Bilayer MoS2 at Various Twist Angles via Folding
| Autor: | Tianhao Yu, Kwanpyo Kim, Yan Zhang, Nan Liu, Xiaojia Du, Yangjin Lee |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Materials science
Fabrication business.industry Bilayer 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences law.invention Folding (chemistry) symbols.namesake chemistry.chemical_compound chemistry law Monolayer symbols Optoelectronics General Materials Science Photolithography Twist 0210 nano-technology business Raman spectroscopy Molybdenum disulfide |
| Zdroj: | ACS Applied Materials & Interfaces. 13:22819-22827 |
| ISSN: | 1944-8252 1944-8244 |
| DOI: | 10.1021/acsami.1c03135 |
| Popis: | Constructing a bilayer system with defined twist angles is an effective way to engineer the physical properties of two-dimensional (2D) materials, opening up a new research area of twistronics. How to achieve high-quality bilayer 2D materials in a controlled and mass production way is of primary importance to this emerging area. In this work, we present a strategy for the large-scale fabrication of twisted bilayer molybdenum disulfide (MoS2) through photolithography patterning and folding of single-crystal monolayer MoS2. Atomic resolution transmission electron spectroscopy directly confirms that the as-achieved folded bilayer MoS2 is of high quality with targeted twist angles. Various twist angles result in tuning Raman mode frequencies and direct optical transition energies. Due to the weak interlayer coupling between the twisted layers, folded bilayers exhibit an extremely high photoluminescence with doubled intensity as compared to the unfolded monolayer, indicating a possible application in optoelectronic devices. Our work provides a new strategy to tailor the properties of MoS2, which will be beneficial to twistable electronics. |
| Databáze: | OpenAIRE |
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