Tertiary-Amino-Functionalized Resin-Supported Palladium Catalyst for the Heterogeneous Suzuki–Miyaura Reaction of Aryl Chlorides

Autor: Tomoteru Mizusaki, Hironao Sajiki, Tomohiro Hattori, Tomohiro Ichikawa, Yasunari Monguchi, Moeko Netsu, Yoshinari Sawama
Rok vydání: 2015
Předmět:
Zdroj: Synlett. 26:2014-2018
ISSN: 1437-2096
0936-5214
DOI: 10.1055/s-0034-1380443
Popis: A palladium catalyst supported on a tertiary-amino-functionalized resin bearing N,N-dimethylamino substituents on the polystyrene-divinylbenzene-based resin was developed. The catalyst was effectively used for the ligand-free Suzuki–Miyaura reactions of less-reactive chloroarenes with arylboronic acids. No leached palladium species were detected in the reaction media after the reaction.
Databáze: OpenAIRE