Tertiary-Amino-Functionalized Resin-Supported Palladium Catalyst for the Heterogeneous Suzuki–Miyaura Reaction of Aryl Chlorides
Autor: | Tomoteru Mizusaki, Hironao Sajiki, Tomohiro Hattori, Tomohiro Ichikawa, Yasunari Monguchi, Moeko Netsu, Yoshinari Sawama |
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Rok vydání: | 2015 |
Předmět: | |
Zdroj: | Synlett. 26:2014-2018 |
ISSN: | 1437-2096 0936-5214 |
DOI: | 10.1055/s-0034-1380443 |
Popis: | A palladium catalyst supported on a tertiary-amino-functionalized resin bearing N,N-dimethylamino substituents on the polystyrene-divinylbenzene-based resin was developed. The catalyst was effectively used for the ligand-free Suzuki–Miyaura reactions of less-reactive chloroarenes with arylboronic acids. No leached palladium species were detected in the reaction media after the reaction. |
Databáze: | OpenAIRE |
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