A facile synthesis of homochiral 1-norbornanecarboxylic acids and 1-norbornanecarbonitriles

Autor:	E. Teso Vilar, L. R. Subramanian, A. Garcia Martinez, J. M. Gonzalez-Fleitas De Diego, A. Garcia Fraile, S. De La Moya Cerero
Rok vydání:	1994
Předmět:	chemistry.chemical_classification Wagner–Meerwein rearrangement Ketone General method Bicyclic molecule Monoterpene Organic Chemistry Catalysis Inorganic Chemistry Camphor chemistry.chemical_compound chemistry Organic chemistry Physical and Theoretical Chemistry Cyanohydrin
Zdroj:	Tetrahedron: Asymmetry. 5:1599-1603
ISSN:	0957-4166
DOI:	10.1016/0957-4166(94)80130-4
Popis:	A general method for the preparation of the title compounds from naturally occurring homochiral 2-norbornanones is presented. The key step is the Tf 2 O induced Wagner-Meerwein rearrangement of the corresponding cyanohydrins.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::39cb6d6986d9890673141a687924de24 https://doi.org/10.1016/0957-4166(94)80130-4 Zobrazit plný text záznamu