Ca(CF3COO)2: An efficient Lewis acid catalyst for chemo- and regio-selective enamination of β-dicarbonyl compounds

Autor:	Abdallah Karim, Mustapha Ait Ali, Alain Roucoux, Mohamed Anoir Harrad, Larbi El Firdoussi, Rachid Outtouch
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Solvent free Primary (chemistry) Chemistry Process Chemistry and Technology Organic chemistry General Chemistry Catalysis Lewis acid catalysis Enamine
Zdroj:	Catalysis Communications. 11:442-446
ISSN:	1566-7367
DOI:	10.1016/j.catcom.2009.11.019
Popis:	A relevant procedure has been developed for the synthesis of β-enaminoesters catalysed by Ca(CF 3 COO) 2 . The reaction of β-ketoesters with primary amines was efficiently carried out under solvent-free conditions at room temperature and led to chemo- and regio-selective formations of enamine derivatives in high yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::39bd27bbe463027f2df7721a7e335cd9 https://doi.org/10.1016/j.catcom.2009.11.019 Zobrazit plný text záznamu Full Text from ScienceDirect