Preparation and reactions of tetrahydridotris(triphenylphosphine)ruthenium(IV)

Autor:	R.O. Harris, L. Sadavoy, J.M.C. Yuen, N.K. Hota
Rok vydání:	1973
Předmět:	Hydrogen Ligand Organic Chemistry chemistry.chemical_element Biochemistry Medicinal chemistry Small molecule Ruthenium Inorganic Chemistry Sodium borohydride chemistry.chemical_compound chemistry Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Triphenylphosphine
Zdroj:	Journal of Organometallic Chemistry. 54:259-264
ISSN:	0022-328X
Popis:	The reduction of RuCl2(PPh3)3) by sodium borohydride produces RuH4(PPh3)3. Small molecules react with this complex in several ways. They add with replacement of hydrogen (N2, CO, NO); they are reduced (C2H4) or they insert into a metal-hydride bond (CS2). Chemical evidence for the presence of a dithioformato ligand is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::39a872fff99534cd5b58a927b8f5e915 https://doi.org/10.1016/s0022-328x(00)85017-2 Zobrazit plný text záznamu