Electrochemical Studies of the Mechanism of the Formation of Metal‐TCNQ Charge‐Transfer Complex Film
| Autor: | Dwaine O. Cowan, Jerome Kruger, Hailing Duan |
|---|---|
| Rok vydání: | 1993 |
| Předmět: |
Renewable Energy
Sustainability and the Environment Stereochemistry Chemistry Scanning electron microscope Diffusion Condensed Matter Physics Electrochemistry Charge-transfer complex Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal chemistry.chemical_compound visual_art Electrode Materials Chemistry visual_art.visual_art_medium Physical chemistry Thin film Acetonitrile |
| Zdroj: | Journal of The Electrochemical Society. 140:2807-2815 |
| ISSN: | 1945-7111 0013-4651 |
| DOI: | 10.1149/1.2220914 |
| Popis: | Switching and memory storage thin films constructed from metallorganic charge-transfer complexes, such as Cu + TCNQ - , can be prepared by reacting metals directly with organic acceptors in an acetonitrile solution. SEM and electrochemical methods were used to study the formation process of Cu + TCNQ - films on Cu substrates in a TCNQ/acetonitrile solution. These studies show that the Cu + TCNQ - films are formed via a localized corrosion-crystallization process, and the electrode system of Cu/Cu + TCNQ - , TCNQ 0 (CH 3 CN) is an active-passive system corroding under diffusion control |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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