Fluorous Phase Soluble Palladium Nanoparticles as Recoverable Catalysts for Suzuki Cross-Coupling and Heck Reactions

Autor:	Marcial Moreno-Mañas, Silvia Villarroya, and Roser Pleixats
Rok vydání:	2001
Předmět:	Organic Chemistry Nanoparticle chemistry.chemical_element Catalysis Inorganic Chemistry chemistry.chemical_compound Colloid chemistry Transmission electron microscopy Heck reaction Phase (matter) Organic chemistry Methanol Physical and Theoretical Chemistry Palladium
Zdroj:	Organometallics. 20:4524-4528
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om010442z
Popis:	1,5-Bis(4,4‘-bis(perfluorooctyl)phenyl)-1,4-pentadien-3-one stabilizes palladium(0) nanoparticles (transmission electron microscopy) formed in the reduction of palladium dichloride with methanol. These palladium colloids are soluble in perfluorinated solvents, and they are efficient recoverable catalysts for Suzuki cross-couplings and Heck reactions under fluorous biphasic conditions.
Databáze:	OpenAIRE
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