Synthesis and photolysis studies of carboxylic esters of 2-hydroxy-1,2,2-triphenylethanone: a novel tandem photocyclisation
Autor: | Alex Mullaney, Natalie Kelly, Iwan Williams, Matthew A. Jones, M. Arfan Ashraf, John S. Snaith |
---|---|
Rok vydání: | 2003 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 44:3151-3154 |
ISSN: | 0040-4039 |
Popis: | Carboxylic esters of 2-hydroxy-1,2,2-triphenylethanone can be prepared in good yield by reaction between 2-chloro-1,2,2-triphenylethanone and a carboxylic acid in the presence of silver carbonate and silver tetrafluoroborate. Irradiation of the ester with a medium pressure mercury lamp results in a rapid and quantitative photolysis to afford the carboxylic acid and benzo[b]phenanthro[9,10-d]furan. |
Databáze: | OpenAIRE |
Externí odkaz: |