Synthesis and photolysis studies of carboxylic esters of 2-hydroxy-1,2,2-triphenylethanone: a novel tandem photocyclisation

Autor: Alex Mullaney, Natalie Kelly, Iwan Williams, Matthew A. Jones, M. Arfan Ashraf, John S. Snaith
Rok vydání: 2003
Předmět:
Zdroj: Tetrahedron Letters. 44:3151-3154
ISSN: 0040-4039
Popis: Carboxylic esters of 2-hydroxy-1,2,2-triphenylethanone can be prepared in good yield by reaction between 2-chloro-1,2,2-triphenylethanone and a carboxylic acid in the presence of silver carbonate and silver tetrafluoroborate. Irradiation of the ester with a medium pressure mercury lamp results in a rapid and quantitative photolysis to afford the carboxylic acid and benzo[b]phenanthro[9,10-d]furan.
Databáze: OpenAIRE