A unique 3D Co(II)-MOF based on [Co6(μ3-OH)4]8+n chains: Synthesis, crystal structure, and magnetic property
Autor: | Zhong-Long Wang, Jian Zhang, Dongsheng Li, Guo-Wang Xu, Guo-Xuan Wen, Sha-Sha Guo |
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Rok vydání: | 2015 |
Předmět: | |
Zdroj: | Inorganic Chemistry Communications. 55:17-20 |
ISSN: | 1387-7003 |
Popis: | A novel metal-organic framework, [Co6(μ3-OH)4(ndc)4(bip)2(H2O)2]n (1)[H2 ndc = 1,4-naphthalenedicarboxylic acid, bip = 1,5-bis(imidazole-1-yl)pentane], constructed from unique [Co6(μ3-OH)4]8 +n chains containing alternate [Co4(OH)2]6 + and [Co2(OH)2]2 + subunits, was reported, which has a new (3,3,8,12)-connected or 12-connented fcu/cubic network and shows weak antiferromagnetic interaction between the adjacent Co(II) ions mediated through the carboxylate and hydroxyl groups. |
Databáze: | OpenAIRE |
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