A unique 3D Co(II)-MOF based on [Co6(μ3-OH)4]8+n chains: Synthesis, crystal structure, and magnetic property

Autor:	Zhong-Long Wang, Jian Zhang, Dongsheng Li, Guo-Wang Xu, Guo-Xuan Wen, Sha-Sha Guo
Rok vydání:	2015
Předmět:	Inorganic Chemistry Pentane chemistry.chemical_compound Crystallography chemistry Materials Chemistry Antiferromagnetism Carboxylate Crystal structure Physical and Theoretical Chemistry Ion
Zdroj:	Inorganic Chemistry Communications. 55:17-20
ISSN:	1387-7003
Popis:	A novel metal-organic framework, [Co6(μ3-OH)4(ndc)4(bip)2(H2O)2]n (1)[H2 ndc = 1,4-naphthalenedicarboxylic acid, bip = 1,5-bis(imidazole-1-yl)pentane], constructed from unique [Co6(μ3-OH)4]8 +n chains containing alternate [Co4(OH)2]6 + and [Co2(OH)2]2 + subunits, was reported, which has a new (3,3,8,12)-connected or 12-connented fcu/cubic network and shows weak antiferromagnetic interaction between the adjacent Co(II) ions mediated through the carboxylate and hydroxyl groups.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::39905b4726b1a663db9a48176ba1277e https://doi.org/10.1016/j.inoche.2015.03.005 Zobrazit plný text záznamu Full Text from ScienceDirect