pH-dependent extraction of soil and soil amendments to understand the factors controlling element mobility

Autor: H.A. van der Sloot, C. M. Carter, D. Cooling
Rok vydání: 2009
Předmět:
Zdroj: European Journal of Soil Science. 60:622-637
ISSN: 1351-0754
DOI: 10.1111/j.1365-2389.2009.01139.x
Popis: Summary A combination of the pH-dependent leaching test CEN/TS 14429 and geochemical modelling (LeachXS©-ORCHESTRA) was used to evaluate the partitioning of major, minor and trace elements in relation to their phosphorus retention capability, the release of non-nutrient constituents, their reduction of soil acidity and their organic matter retention. One Australian soil sample and two different soil amendments (Red Lime and Alkaloam) were studied. The pH-dependent leaching test showed that the acid neutralization capacity and the phosphorus retention of the soil were improved, respectively, by a factor of two to five and by a factor of two to ten after addition of these amendments. The amendments improved retention of dissolved organic matter (by a factor of 3–10) and did not increase leachability of undesired contaminants. The partitioning as obtained from modelling between free and dissolved organic-carbon-bound metals provides insight into the potential for uptake (bioavailability). This partitioning is very pH-dependent and therefore testing and associated chemical speciation modelling provide valuable information for judging traditional soil improvers and soil amendments, including the waste-derived soil amendments Alkaloam and Red Lime.
Databáze: OpenAIRE