Analysis of mixtures of six carbon unsaturates

Autor: R. W. Dunning, J. A. Leonard
Rok vydání: 1969
Předmět:
Zdroj: Chromatographia. 2:293-297
ISSN: 1612-1112
0009-5893
DOI: 10.1007/bf02258966
Popis: Practical resolution of twelve hexene isomers is described. Total analysis time is forty minutes and separation is effected by means of a 100 metre squalane coated capillary column maintained at 0°C. Details of a technique allowing the rapid determination of the skeletal distribution of these isomers is given. Olefins are hydrogenated via a catalyst-containing liner which is itself part of a modified injection block. Hydrogen is used both as reactant and carrier gas in this process.
Databáze: OpenAIRE