Electrochemical Oxidation of Trifluoroacetic Acid in an Organic Substrate. III. In the Presence of Substituted Malonic Acid Half Esters and Unsaturated Carboxylic Acid Esters

Autor:	Philippe J. Champagne, Roger N. Renaud
Rok vydání:	1975
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Carboxylic acid Organic Chemistry Trifluoroacetic acid Organic chemistry Substrate (chemistry) General Chemistry Malonic acid Electrochemistry Catalysis
Zdroj:	Canadian Journal of Chemistry. 53:529-534
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v75-072
Popis:	The electrochemical oxidation of substituted malonic acid half-esters was studied in the presence of trifluoroacetic acid. Some 'crossed' Kolbe products were obtained together with some unsaturated carboalkoxy compounds, trifluoromethylated adducts to the double bond, and trifluoromethylated dimers.The electrolysis of trifluoroacetic acid in the presence of olefinic carboalkoxy compounds was also studied.
Databáze:	OpenAIRE
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