Synthesis and vibrational analysis of new bismuth phosphate glasses
| Autor: | Z. Ramzi, K. Benkhouja, Samira Touhtouh, Wafaa Nachit, Abdelowahed Hajjaji |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Hydrogen
Ammonium phosphate 020209 energy Inorganic chemistry Oxide Analytical chemistry chemistry.chemical_element Infrared spectroscopy 02 engineering and technology 021001 nanoscience & nanotechnology Phosphate Atomic and Molecular Physics and Optics Analytical Chemistry Bismuth chemistry.chemical_compound Molar volume chemistry 0202 electrical engineering electronic engineering information engineering Fourier transform infrared spectroscopy 0210 nano-technology Spectroscopy |
| Zdroj: | Spectroscopy Letters. 50:200-205 |
| ISSN: | 1532-2289 0038-7010 |
| DOI: | 10.1080/00387010.2017.1282524 |
| Popis: | Bismuth phosphate glasses were prepared using the conventional melt quenching technique with a mixture of Bismuth(III) oxide and hydrogen ammonium phosphate. The amorphous state of the samples was verified by X-ray diffraction. The physical parameters like molar volume and oxygen packing density were evaluated from the measured density values. It is found that the density increased from 5.45 g/cm3 to 6.12 g/cm3, while the values of the molar volume increased from 34,97 to 39.08 cm3/mol, and whereas the oxygen packing density decreased with the gradual increase of the of bismuth content. The structure of the glasses was determined using Infrared Spectroscopy. The Fourier Transform Infrared Spectroscopy spectra were recorded in the spectral range from 400 to 1400 cm−1. The structural investigations based on these spectra show the rapid depolymerization of phosphate chains with an increase in bismuth oxide. Also, this investigation highlights that the glassy-matrix contains various phosphate and bism... |
| Databáze: | OpenAIRE |
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