Mercury accumulation and speciation in plants and soils from abandoned cinnabar mines

Autor: Sol López-Andrés, Isabel Rucandio, Belén Gómez-Mancebo, Almudena Ordóñez, Jorge Loredo, Isabel Gómez-Pinilla, Raquel Larios, Rodolfo Fernández-Martínez
Rok vydání: 2015
Předmět:
Zdroj: Geoderma. :30-38
ISSN: 0016-7061
DOI: 10.1016/j.geoderma.2015.04.005
Popis: This study examines total Hg, free Hg(0), matrix-bound Hg and MeHg contents in soils and plant tissues from two old cinnabar mining sites (La Soterrana and Los Rueldos) in Asturias (Spain), as well as Hg transfer and translocation from soils to plants. The studied soils from both mines accumulated moderate to very high total Hg concentrations (36–1709 mg·kg− 1) but quite low available Hg contents (0.005–3.062 mg·kg− 1) which resulted in relatively low transfer factor values. Matrix-bound Hg was the prevalent Hg form in soils from both mining sites representing 67–88% of total Hg content. Significant Hg(0) concentrations were found in soils as a consequence of atmospheric deposition. Appreciable MeHg concentrations were found in soils from La Soterrana mining site while non-detectable MeHg could be found in soils from Los Rueldos. All the studied plants can be considered as excluders. Hg(0) is practically absent in roots indicating that this Hg form is not uptaken from soils. Hg(0) contents found in aboveground tissues evidenced that foliar uptake of atmospheric Hg occurs. Significant MeHg contents were found in the aerial parts for all studied plants. However, MeHg contents in roots were extremely low in La Soterrana plants and non-detectable in those from Los Rueldos.
Databáze: OpenAIRE