Solid state fluorescence of a 3,4,9,10-perylenetetracarboxylic diimide derivative encapsulated in the pores of mesoporous silica MCM-41

Autor:	Francisco L. Castro, Valter J. Fernandes, Antonio S. Araujo, Sergio Brochsztain, Glauber José Turolla Fernandes, Mário José Politi, Jean G. dos Santos
Rok vydání:	2007
Předmět:	Aqueous solution Materials science Nanowire Nanotechnology General Chemistry Mesoporous silica Condensed Matter Physics Fluorescence chemistry.chemical_compound chemistry MCM-41 Chemical engineering Mechanics of Materials Diimide General Materials Science Diffuse reflection Perylene
Zdroj:	Microporous and Mesoporous Materials. 102:258-264
ISSN:	1387-1811
DOI:	10.1016/j.micromeso.2006.12.042
Popis:	This work describes the encapsulation of N , N ′-bis(2-phosphonoethyl)-3,4,9,10-perylenetetracarboxylic diimide (PPDI), a water-soluble perylene dye, in the channels of mesoporous silica MCM-41. The incorporation of the dye was achieved by stirring MCM-41 with aqueous solutions of PPDI. The solid material obtained by this process exhibited a red fluorescence. Diffuse reflectance and emission spectra of the fluorescent powder suggested a highly organized arrangement with the PPDI molecules self-assembled in a 1D stack inside the channels of the mesoporous silica. The new materials described here have potential applications as nanoscale optoelectronic devices, such as conducting nanowires and fluorescent gas sensors.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::394a16e7595331e956fe693c0bb6928b https://doi.org/10.1016/j.micromeso.2006.12.042 Zobrazit plný text záznamu Full Text from ScienceDirect