Infrared diode laser study of the kinetics of the NCCO+O2 reaction

Autor:	John F. Hershberger, Wenhui Feng
Rok vydání:	2010
Předmět:	Infrared Branching fraction Chemistry Kinetics Analytical chemistry General Physics and Astronomy Fundamental frequency Laser law.invention Reaction rate constant law Physical and Theoretical Chemistry Total pressure Diode
Zdroj:	Chemical Physics Letters. 488:140-144
ISSN:	0009-2614
Popis:	Infrared diode laser spectroscopy was used to probe the kinetics of the NCCO + O 2 reaction. Several NCCO transitions were detected at 1887–1890 cm −1 , in good agreement with a recent high-level calculation for the ν 2 fundamental vibrational frequency. The total rate constant of the NCCO + O 2 reaction was measured to be (5.2 ± 0.5) × 10 −13 cm 3 molecule −1 s −1 at 2 Torr pressure of N 2 . The NCO + CO 2 product channel was detected for the first time by probing 18 OC 16 O products from NCCO + 18 O 2 . The branching ratio for this channel was estimated to be 0.28 ± 0.06 at 3.2 Torr total pressure.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::39494d9f533aef011d71b49d5aa1d632 https://doi.org/10.1016/j.cplett.2010.02.029 Zobrazit plný text záznamu Full Text from ScienceDirect