Autor:	Peter Legzdins, Kevin M. Smith, McNeil Ws
Rok vydání:	2000
Předmět:	Chemistry Ligand Organic Chemistry General Chemistry Photochemistry Pi bond Catalysis Metal Atomic orbital Oxidation state Computational chemistry visual_art visual_art.visual_art_medium Molecule Reactivity (chemistry) Group 2 organometallic chemistry
Zdroj:	Chemistry - A European Journal. 6:1525-1529
ISSN:	1521-3765 0947-6539
DOI:	10.1002/(sici)1521-3765(20000502)6:9<1525::aid-chem1525>3.3.co;2-j
Popis:	Recent synthetic and theoretical investigations of organometallic compounds containing the CpCr(NO) fragment have shown an interdependence of the electronic nature of ancillary ligands and the stability of a given Cr oxidation state. Understanding the correlation between ligand pi-bonding properties and the nature of the metal-based frontier orbitals permits the rationalization of observed reactivity patterns, and the identification and preparation of new classes of target molecules.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3944568518571bcd6e08a39f712f399c https://doi.org/10.1002/(sici)1521-3765(20000502)6:9<1525::aid-chem1525>3.3.co Zobrazit plný text záznamu Plný text