Unimolecular HBr and HF Elimination Reactions of Vibrationally Excited C2H5CH2Br and C2D5CHFBr: Identification of the 1,1-HBr Elimination Reaction from C2D5CHFBr and Search for the C2D5(F)C:HBr Adduct

Autor:	George L. Heard, Mallory M. Rothrock, Blanton R. Gillespie, Bert E. Holmes, Anthony J. Ranieri, Melinda K. Schueneman, Donald W. Setser, Timothy M. Brown
Rok vydání:	2019
Předmět:	Elimination reaction Vibrational energy Chemistry Computational chemistry Excited state Physical and Theoretical Chemistry Adduct
Zdroj:	The Journal of Physical Chemistry A. 123:8776-8786
ISSN:	1520-5215 1089-5639
DOI:	10.1021/acs.jpca.9b07029
Popis:	Chemical activation experiments and computational methods have been used to study the unimolecular reactions of C2H5CH2Br and C2D5CHFBr with 90 and 93 kcal mol–1 of vibrational energy, respectively...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3928cb3964ed0c80084e99e81a140c00 https://doi.org/10.1021/acs.jpca.9b07029 Zobrazit plný text záznamu