Functional Group Chemistry at the Group 4 Bent Metallocene Framework: [2+2] Cycloaddition of the Parent Bis(vinyl-Cp/vinyl-Ind)ZrCl2 Systems

Autor:	Gerald Kehr, Ingo Greger, Gerhard Erker, Roland Fröhlich
Rok vydání:	2010
Předmět:	Zirconium Stereochemistry Chemistry Organic Chemistry Bent metallocene chemistry.chemical_element Medicinal chemistry Cycloaddition Inorganic Chemistry chemistry.chemical_compound Group (periodic table) Yield (chemistry) Intramolecular force Functional group Physical and Theoretical Chemistry
Zdroj:	Organometallics. 29:860-866
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om900939v
Popis:	Bis(vinyl-Cp)zirconium dichloride (6) undergoes a clean intramolecular photochemically induced [2+2] cycloaddition reaction to yield the cyclobutylene-bridged ansa-zirconocene isomer (7) when irrad...
Databáze:	OpenAIRE
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