Effect of the composition of the immobilized copper-containing ionic liquid on the dodecyl mercaptan oxidation kinetics
| Autor: | O. I. Vernaya, S. V. Verzhichinskaya, Alexey K. Buryak, L. A. Tyurina, V. M. Zelikman, T. V. Bukharkina, R. Z. Sakhabutdinov, Irina Tarkhanova, R. M. Garifullin |
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| Rok vydání: | 2017 |
| Předmět: |
Stripping (chemistry)
010405 organic chemistry Hydrogen sulfide Kinetics Inorganic chemistry chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Copper Catalysis 0104 chemical sciences Computer Science Applications chemistry.chemical_compound Catalytic oxidation chemistry Modeling and Simulation Ionic liquid Pyridinium |
| Zdroj: | Kinetics and Catalysis. 58:362-369 |
| ISSN: | 1608-3210 0023-1584 |
| DOI: | 10.1134/s002315841704019x |
| Popis: | Basic kinetic parameters of the catalytic oxidation of dodecyl mercaptan in kerosene in the presence of silica-immobilized pyridinium or imidazolium chlorocuprate complexes have been determined. The composition of the copper-containing anions and the oxidation kinetics depend on the nature of the ionic liquid and on the method of its synthesis. The compositions developed in this study are usable in the removal of hydrogen sulfide and light mercaptans from the oil stripping gas. |
| Databáze: | OpenAIRE |
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