Synthesis and study of a polymer containing di- and triazenyl-p-phenylene groups

Autor:	A.A. Durgaryan, N. A. Durgaryan, R. A. Arakelyan, E. E. Matinyan
Rok vydání:	2014
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Electrical resistivity and conductivity Iodine doping Phenylene Doping Polymer chemistry General Chemistry Polymer Perchloric acid
Zdroj:	Russian Journal of General Chemistry. 84:860-864
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363214050132
Popis:	A polymer containing di- and triazenyl-p-phenylene groups in the main chain was synthesized for the first time. Doping of newly synthesized poly(triazene-1,3-diyl-p-phenylenes) and poly(triazene-1,3-diyl-pdiphenylenes) with perchloric acid is studied. The introduction of azophenylene groups in the chain of a polymer containing triazenylphenylene groups has almost no effect on electrical conductivity. The electrical conductivity of these polymers increases from 10−9 to 0.8 S/m with increasing doping degree. The replacement of phenylene by diphenylene groups slightly reduces the electrical conductivity of the polymer doped with perchloric acid, while in the case of iodine doping, by contrast, the electrical conductivity slightly increases.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::38d857a8774a50cc18280bab37315953 https://doi.org/10.1134/s1070363214050132 Zobrazit plný text záznamu Plný text ve formátu PDF