Diastereomer Ratio of Products as a Mechanistic Probe in Epimerization and Ligand Exchange of Chiral-at-Metal [CpFe(Prophos)NCMe]X (X = I, PF6)

Autor:	Henri Brunner, Manfred Muschiol, Manfred Zabel, Hayato Ike, Kazuhiro Koyama, Takaki Kurosawa, Takashi Tsuno
Rok vydání:	2011
Předmět:	Inorganic Chemistry Metal chemistry.chemical_compound Stereochemistry Chemistry Ligand visual_art Organic Chemistry visual_art.visual_art_medium Diastereomer Epimer Physical and Theoretical Chemistry Acetonitrile
Zdroj:	Organometallics. 30:3666-3676
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om2003893
Popis:	The diastereomers (RFe,RC)/(SFe,RC)-[CpFe(Prophos)NCMe]X (X = I, PF6), 5:95, differing only in the metal configuration, were prepared from (RFe,RC)/(SFe,RC)-[CpFe(Prophos)I] (95:5) in acetonitrile ...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::38bba47e094f85c4a0102b1ff7e5ce0c https://doi.org/10.1021/om2003893 Zobrazit plný text záznamu