Anodic polarisation of the lithium/lithium nitride interface

Autor: M.F. Bell, U.v. Alpen
Rok vydání: 1981
Předmět:
Zdroj: Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 129:315-319
ISSN: 0022-0728
DOI: 10.1016/s0022-0728(81)80022-8
Popis: The kinetics of lithium transport across the interface formed by melting lithium on to a lithium nitride sinter has been studied using a linear potential sweep technique. The current-voltage curve obtained was corrected for the ohmic resistance obtained from the high-frequency intercept of the complex plane impedance diagram measured at E=0 mV (vs. a Li/Li+ reference electrode). A model which allows the calculation of the product of concentration and diffusion coefficient to be calculated is proposed to account for the observed behaviour.
Databáze: OpenAIRE