Zur paramagnetischen Elektronenresonanz metallorganischer Sandwich-Verbindungen, Teil II / The Magnetic Resonance Properties of Some Sandwich Compounds, part II

Autor:	Robert Krieger, Jürgen Voitländer
Rok vydání:	1972
Předmět:	Crystallography Materials science medicine.diagnostic_test medicine General Physics and Astronomy Magnetic resonance imaging Physical and Theoretical Chemistry Mathematical Physics
Zdroj:	Zeitschrift für Naturforschung A. 27:1444-1455
ISSN:	1865-7109 0932-0784
DOI:	10.1515/zna-1972-1011
Popis:	In part II the magnetic resonance properties of the lowest lying excited triplet state of ferrocene has been investigated theoretically. As in the case of the ground state of chromocene (part I) we studied the splitting of the orbitally degenerate triplet state by the combined action of spin-orbit coupling and low-symmetry perturbation. The results explain the fact that no ESR spectrum has been observed in the lowest lying triplet state of ferrocene until now. There is also given an estimation of the lifetime of this state. The g-values and parameters of hyperfinestructure of the orbitally degenerate doublet ground state of cobaltocene are calculated and compared with the experimental results. The wave functions used for the calculations were obtained by a self-consistent-charge extended Hückel method.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::3892678face410f4fb052ee53dd7e929 https://doi.org/10.1515/zna-1972-1011 Zobrazit plný text záznamu