Copper(I) catalysis: Synthesis of N,N′-diarylated and N-aryl,N′-formylated chiral C2-symmetric diamines

Autor:	Laxhmaiah Alakonda, Mariappan Periasamy
Rok vydání:	2009
Předmět:	Stereochemistry Aryl Organic Chemistry Iodobenzene chemistry.chemical_element Biochemistry Copper Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Yield (chemistry) Materials Chemistry Copper catalyzed Physical and Theoretical Chemistry Derivative (chemistry)
Zdroj:	Journal of Organometallic Chemistry. 694:3859-3863
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2009.08.002
Popis:	Chiral N , N ′ - diaryl C 2 -symmetric diamines and N -aryl, N ′-formyl -trans -(1 R ,2 R )-diaminocyclohexane are readily accessed by copper catalyzed N , N ′ - diarylation and N -aryl, N ′-formylation of trans -(1 R ,2 R )-diaminocyclohexane with aryl bromides. N , N ′-diarylation using ( R )-1,1′-binaphthyl-2,2′-diamine and iodobenzene gave the corresponding ( R )- N , N ′ - diphenyl-1,1′-binaphthyl-2,2′-diamine derivative in 83% yield.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::38925ce2fc7f213af59518731f351cfc https://doi.org/10.1016/j.jorganchem.2009.08.002 Zobrazit plný text záznamu Full Text from ScienceDirect