N/O- and C-Bound (Enolato)palladium Complexes with Hydrotris(pyrazolyl)borato Ligands (TpR: R = iPr2, Me2) Obtained via Dehydrative Condensation between the Hydroxo Complexes TpRPd(Py)OH and Active Methylene Compounds: Factors Determining the Isomer Distribution and Dimerization of Cyano Compounds

Autor:	Munetaka Akita, Shiro Hikichi, Masato Kujime
Rok vydání:	2001
Předmět:	Inorganic Chemistry chemistry.chemical_compound Stereochemistry Chemistry Ligand Organic Chemistry Condensation Dicyanomethane chemistry.chemical_element Physical and Theoretical Chemistry Methylene Medicinal chemistry Palladium
Zdroj:	Organometallics. 20:4049-4060
ISSN:	1520-6041 0276-7333
Popis:	Reaction of a hydroxopalladium complex bearing the TpiPr2 ligand, (TpiPr2)(py)Pd−OH (1iPr2), with active methylene compounds, X−CH2−Y 2 [dicyanomethane (2a), methyl cyanoacetate (2b), benzoylaceton...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::386fa65bb9eb302a9a147d5ff1f71742 https://doi.org/10.1021/om010448o Zobrazit plný text záznamu