N/O- and C-Bound (Enolato)palladium Complexes with Hydrotris(pyrazolyl)borato Ligands (TpR: R = iPr2, Me2) Obtained via Dehydrative Condensation between the Hydroxo Complexes TpRPd(Py)OH and Active Methylene Compounds: Factors Determining the Isomer Distribution and Dimerization of Cyano Compounds
Autor: | Munetaka Akita, Shiro Hikichi, Masato Kujime |
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Rok vydání: | 2001 |
Předmět: | |
Zdroj: | Organometallics. 20:4049-4060 |
ISSN: | 1520-6041 0276-7333 |
Popis: | Reaction of a hydroxopalladium complex bearing the TpiPr2 ligand, (TpiPr2)(py)Pd−OH (1iPr2), with active methylene compounds, X−CH2−Y 2 [dicyanomethane (2a), methyl cyanoacetate (2b), benzoylaceton... |
Databáze: | OpenAIRE |
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