New 4-carboxylphthalhydrazidate-bridged Mn2+/In3+ coordination polymers
| Autor: | Juan Jin, Chen Lin, Qing-Feng Yang, Wenfu Yan, Bing Liu, Shan-Min Gao, Xiao-Yang Yu, Ji-Qing Xu, Chuan-Zhao Li |
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| Rok vydání: | 2017 |
| Předmět: |
Thermogravimetric analysis
Aqueous solution 010405 organic chemistry Chemistry Organic Chemistry Supramolecular chemistry Infrared spectroscopy 010402 general chemistry Photochemistry 01 natural sciences 0104 chemical sciences Analytical Chemistry Inorganic Chemistry Acylation Crystallography Molecule Antiferromagnetism Spectroscopy Powder diffraction |
| Zdroj: | Journal of Molecular Structure. 1134:728-733 |
| ISSN: | 0022-2860 |
| Popis: | Based on the hydrothermal in situ acylation reaction of benzene-1,2,4-tricarboxylic acid (btca) with N2H4·H2O, two containing-4-carboxylphthalhydrazidate Mn2+/In3+ coordination polymers, [Mn(cpth)(phen)] 1 and [In(cpth)(ox)0.5(phen)]·H2O 2 (cpth = 4-carboxylphthalhydrazidate, phen = 1,10-phenanthroline, ox = oxalate), were obtained and characterized by elemental analysis, IR spectroscopy, X-ray powder diffraction (XRD), thermogravimetric analysis (TGA), and single-crystal X-ray diffraction. In compound 1, the cpth ligands exhibit a μ4-bridging mode, which link Mn(II) centers into a 2-D layer structure with ancillary phen molecules. In compound 2, the cpth ligands exhibit a μ2-bridging mode, which link In(III) centers into a binuclear unit. Ox ligands act as the second linkers, extending binuclear unit into a 1-D chain with ancillary phen molecules. Via N H⋯O interactions, compound 2 self-assembles into a 2-D supramolecular layer. The magnetic analysis indicates that there exists antiferromagnetic interactions between magnetic centers in compound 1. The photoluminescence properties of compounds 1 and 2 were also investigated in an aqueous solution. |
| Databáze: | OpenAIRE |
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